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- , .. () [1], [2, 3].

() , .

(- ), , (3,5-.4- ) [4], . [5] 12 / . () .

, . 2,43,6 . a , , Ni, Co .



, , in vivo.

1. .., .. , 2006, 51, 2, 340.

2. .., .., .. . . .

2004, 44, 3, 289.

3. .., .., .., .., .. , 2007, 52, 4, 693.

4. .., .., .., .., .., . . , 2003, 1, 50.

5. .., .., .. . , 1994, 30, 3, 441.

HBsAg B. Mori

   

, , , , . , . - , , , , . . (HBsAg). HBsAg. () , .





, HBsAg B. mori.

HBsAg (adw, ayw). , - HBsAg ( ). , - ( HBsAg ayw).

, HBsAg . , , , - .

   

. [1].

[2]. .

(Araliaceae Juss.) - ( 1) ( 2). 1 3---L--(12)---L- , 2 3---L--(12)---L--28---L--(14)--D--(16)---D- .

COOR 2 R1O OH 1: R1 = Rhap (12)-Arap, R2 = ;

2: R1 = Rhap (12)-Arap, R2 = Glcp-(61)- Glcp-(41)- Rhap 1 2 Hedera Kalopanax, Aralia elata Acanthopanax sieboldianus [3]. 1 Polyscias dichroostachya [3], 2 Schefflera octophylla [4]. 1 2 , Hedera helix [5].

, 1 2 2:1 (. 1). . -.

   

1, Planorbis corneus ( Planorbidae), 2, Poecilia reticulata (Poeciliidae). 1 , . , 2.

1. .., .., .. , 2007, 77, 10, 867.

2. .., .., .., .., ..

: , , , : - , 2007, 311 .

3. Hostettmann K., Marston A. Saponins. Cambrige: Cambrige University Press, 1995, 548 p.

4. Maeda C., Ohtani K., Kasai R., Yamasaki K., Duc N.M., Nham N.T., Cu G.K.Q. Phytochemistry, 1994, 37, 4, 1131.

5. .., .., .. , 2003, 12, 13.

1,3-

   

3-4-(-2)-4,5--1- 3 3--2--4-(-2) 4, 99% A.

<

   

1. Hegde S.S., Chandler J., Yu M., Blanchard J.S. Biochemistry. 2007, 46, 7187.

2. Bolognesi M.L., Calonghi N., Masotti L., Melchiorre C. J. Med. Chem. 2008, 51, 5463.

3. Green J.J., Zhou B.Y., Mitalipova M.M., Beard C., Langer R., Jaenisch R., Anderson D.G.

Nano Lett. 2008, 8, 3126.

-

.. , .. , .. , .. , ..

   

(-)-, , , , , (nAChRs). , .

(-)- - . 1,4- 333 K. () (), (wi) 3.410-8 -1-1 ([] = 6.410-3 -1). 1,4 . (-)- , .

:

[O2] = k2(k7)-1[RH]ln(1 t/), (1) [O2] , . k7 k2 = 9,48 -1-1. (-)- (1,48,6)10-3 -1. [O2] ln(1 t/) (-) k7 = (2.80.8)103 -1-1.

, (-)- , . 6- [1] [2].

1. .., .., .., .., .., .., .. . , . ., 2010, 3 ( ).

2. .., .., .., .., .. -2008

0711 2008 , , 311.

,

   

[1] , 1,2,4,5 6.

. 2a 2b - - 3a,b 4a,b . 5a 5b. 2- 7a 7b 2-- 8a 8b. 9a 9b. 2))- 2-(()- 10a,b 11a,b . [2] - 13a 13b.

- , N- .

1. Ivachtchenko A.V., Yamanushkin P.M., Mitkin O.D., Mend. Comm, 2010, .

2. Grinev A. N., Rostova N. I. et al., Pharmaceutical Chemistry J. 1981, 15, 28.

1 13 .. , .. , .. , .. , ..

   

1,3- -1--, , , .

- , 1,3 = [1].

13. , CDCl3 , . 1 1:1 0.13 = 6.41, 6.13 5.82 .. 3.75 3.77 ..

. , 1,3- .

1. .., .., .., .., .., .. , , 2007, 209.

2,3-

.. , .. , .. , ..

   

, , , . , - , , . .

3, -2,3- 1 . , , , in situ.

   

3 - 1--3- ([bmim][BF4]) 4 30%.

-1725.2008.3 7 .

   

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()[4]: - 8 .., .., .., ..

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.11 .., .., .

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…14 .., .., .., .., .., ..

.

15 .., .., .., .., ..

Ʌ.17 .., .., .., .., .., .., .., ..

11-19 .., .., .., ..

5-,

1,2,4-…21 ..

STEVIA REBAUDIANA Յ..23 .., .., .., ..

. ۅ..25 ..

߅....26 ..

…28 .., .., ..

ۅ..29 .., .., ..

1,2- 1,2-….31 .., .., .., .., ..

ۅ.33 .., .., .., ..

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PASS.36 ..

…..38 .., ..

Ņ..39

   

.., ..

…42 .., .., .., .., .., . .

N--4,8-- -4- 3a,4,5,9b--3-[c] ..43 .., .., .., .., ..

:

Ʌ..45 .., .., .., .., .., .., ..

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….49 ..

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.53 .., .., ..

.55 .., .., .., .., .., ..

..57 . .

: 5-ۅ..58 .. ..

-

N,N- ۅ...61 .., .., .., ..

-

ȅ63 . ., . ., .., . ., . ., . ., . .

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:

5-6 …...65 ., .., .., .., ..

ALCEAE NUDIFLORA66 .., .., .., ..

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3,5,8-[5.1.0]…...67 .., ..

…..68 .., .., ..

20-

….70 .., .., .., .., ..

,

-

…..71 .., .., .., .., ..

….73 .., .., ..

-

E. COLI.74 .., .., ..

- ,-̅...75 .., .., .., .., ..

ۅ...76 ..

…78 .., .., .., .., .., .., ..

1-

(3--8-) , ˅..79 .., .., .., .., .., .., ..

,

ȅ...80 .., .., ..

[BMIM]PF6 2-(RS)- -.81 .., .., .., .., .., .., .., ..

31- 82

   

Bets L., Ribkovskaia Z., Vlad L., Freund M., Zamfir A., Wei S., Tsogoeva S.B., Macaev F.Z.

SYNTHESIS OF NEW (+)-3-CARENE DERIVATIVES AND

EVALUATION OF THEIR CATALYTIC EFFICIENCY FOR EPOXIDE

RING OPENING REACTION...86 Dulcevscaia G., Yudin T., Sargorovschi V., Stingaci E., Kravtsov V.Ch., Baca S.G., Pogrebnoi S., Macaev F.

SYNTHESIS AND STRUCTURE OF COPPER(II) COMPLEX

WITH ECONALOZE.87 Radul O., Yudin T., Stingaci E., Pogrebnoi S., Macaev F.

MONONITRILE-FUNCTIONALIZED IONIC LIQUID CATALYZED

EFFICIENT ONE-POT SYNTHESIS OF 2-PYRROLO-3-YLOXINDOLES88 Sucman N.

KINETIC RESOLUTION OF SPIROCYCLOPROPANE-1,3-OXINDOLES89 .., .

RHINOPETALIUM BUCHARICUM...90 .., .., ..

YxDy(1-x)TaO4 LaTaO491 .., .., .., .., .., .., .., ..

ȅ..93 .., .., ..

-

.95 .., .., .., .., .., ..

߅97 .., .., .., .., .., ..

,

ۅ..98 .., .., .., ..

(+)-(S)-2-[(1R,5S), (-)-(S)-2-[(1S,5R) (-)-(R)-2-[(1S,5R)-(3,7--2,4,6,8-[3.3.0] -2-)]-4- ۅ.100 .., .., .., .., ..

2-(2-)-4 -2,4,6,8-[3.3.0]-3,7-.102 .., .., .., ..

2,6--4,8[3.3.0]-3,7 ()...104 .., ..

̅.106 .., .., .., .., .., .., ..

ȅ..108 .., .., .., ..

IN VITRO..109 .., ., .., ..

HAPLOPHYLLUM PEDICELLATUM

܅.111 .., .., .., .., .., ..

,

ۅ...113 .., .., ..

,

҅...114 .., .., ..

.116 .., .., .., .., ..

1,1-[3-()-2--3,5]…..117 .., .., .., .., ..

5-M-1-[2-()-1-()-]-2,9[3.3.1]-4-118 .. (.), .., .., ..

ۅ119 .., .., .., ..

C

..120 .., .., .., .., ..

-1,3-[4,5-D]-2,5(1H,3H) -1,3-[4,5-D]H,3H)-...121 .., ., ., ..

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[1,6-b] 2,3- ۅ...124 .., .., .., .., .., ..

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,- -ȅ127 .., .., .., ..

…128 .., .., ..

.129 .., .., ..

- ...131 .., .., .., ..

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…...133 .., .., ..

...135 .., .., .., ..

1,2,4,5-: ܅...136 .., .., .., .., ..

-, -

L- ,- -̅.137 .., .., .., .., ..

14-

20-138 .., .., .., .., ..

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1--2--1,2,3,4-….143 .., .., .., ..

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….146 .., .., .., .., ..

߅..148 .., .., .., .., .., .., .., .., .., ..

-, -, - ҅..149 .., ., .., ..

11-

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Ʌ.153 .., .., .., ..

(VI)...154 .., .., ..

2+2-

̅155 .., .., .., .., ..

-5- 1,3,6-..156 .., ..

-

ALLIUM CEPA L..157 .., .., ..

….158 .., ..

ACONITUM SEPTENTRIONALE ().160 .., .., .., .., ..

Ȼ, ON/OFF

Ʌ161 .., .., .., ..

…..163 .., .., ..

ۅ..165 .., .., .., .., ..

(-)-

….166 ..

FERULA VARIA ...167 .., .., ..

ȅ..168 .., ..

…..170 .., .., .., ., .., .., .., .., ..

…171 .., .., .., .., .., ..

…173 .., .., ..

ۅ..174 .., .., .., ..

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D- D-Ӆ176 .., .., .., .., .., .., ..

Dy1-xYxTaO4..178 .., .., .., .., .., .., ..

…179 .., .., ..

....181 .., .., .., ..

(1S,2S)- (1R,2R)- -2 ۅ.182 .., .., .., ..

N-4-[2-(2--1,2--3--3)]183 .., .., ..

.185 .., .., .., .., .., .., .., ..

3--5-, ˅.186 .., .., .., .., .., .., ..

, ,

5-6 ̅...187 .., .., .., .., ..

3-[1,5-]….189 .., .., .., .., .., .., .., .., ..

…..190 .., .., ..

-

--ȅ..192 .., .., .., ..

ȅ...194 .., .., .., .., .., ..

ۅ...195 .., .., .., ..

N- ҅196 .., .., .., .., ..

4-3,1- - ȅ..197 .., ..

N- 2(1)-…199 .., .., ..

CANDIDA ALBICANS...200 .., ..

…201 .., .., ..

̅202 .., .., ..

6--2,4-…..204 .., .., .., ..

ȅ...205 ..

߅..207 .., ..

Ņ209 .., .., ..

2,3--7,8--1,4- Ņ210 .., .., .., .., .., ..

…..211 .., .., .., .., .., .., .., .., ..

ۅ213 .., .., .., ..

..214 .., .., .., .., .., ..

- 5-6

2,6- 5,7--3-[1,5-]….215 .., .., .., .., .., ..

3-()[1,5-], 5-6 …216 .., ..

-

̅...218 . ., . ., . ., . ., . ., .

...219 .., .., ..

Cu(II), Zn(II) ...221 .., .., .., .., .., ..

(R)-3-

..222 .., .., ..

-

-

Յ..223 .., .., ..

...225 .., .., ..

1...226 .., .., ..

ȅ...228 .., .., .., ..

-

5-.229 .., .., ..

, ȅ..231 .., .., .., .., .., ..

…232 .., .., .

.233 ., ., ., ..

,

IN VITRO...234.

.., .., .., .., ..

܅...235 .., .., .., ..

N-

237 .., .., ..

5---3-[5.2.1.02,6]-4- ܅..238 .., .., . .

5---3-[5.2.1.02,6]-4- ȅ...239 .., ..

(NP 001008413.2)..241 .., ..

Ʌ.242 ..

.244 .., .., .., ..

,

…..246 .., .., .., .., . .

ȅ247 .., ., ..

(Phellodendron amurense Rupr., var. lavallei)....248 .., .., .., ..

-

ȅ...249 .., .., .., .., ..

(-)- -..251 .., .., ..

1--1,2,3,4-...252 ..

-

Ņ.253 ..

Å...254 .., .., .., .., .., .., ..

3--6,7,8,9-[1,5-] [3,4-e] 3--5,6,7,8-[1,5-][3,4-d] - 5-6 …255 .., .., .., ..

5-

.256 .., .., .., ..

߅.257 .., .., .., . ȅ.258 .., .., .., ..

٨ 3- 3-

Ʌ...260 .., .., ..

N-

(-)-262 .., ..

٨

҅...263 .., ..

N--2-(2--4-)-4- ...265 .., .., ..

߅...266 .., .., .., .., .., ..

...267 .., .., ..

- ̅268 .., .., ..

60

…..269 .., .., .., .., .., ..

,

҅271 .., ..

ȅ...273 .., .., ..

-

…..274 .., .., .., .., ..

IN VITRO...275 .., ..

N-1- ̅276 .., ..

3-(2-)-5--1,2,4-

Ʌ.278 .., ..

҅280 .., .., ..

Յ.281 ..

: ҅..282 .., .., .

HAPLOPHYLLUM GRIFFITHIANUM:

CT …284 .., .., ..

Յ285 .., .., .., ..

..286 .., .., .., ..

..287 .., .., .., ..

….289 .., .., ..

Ʌ..290 .., .., .., ..

ۅ.291 .., .., ..

- ȅ292 ..

1,2,4-[3,4-B][1,3,4] 3- ۅ.293 .., .., .., .., ..

-

- .294 .., .., .., .., .., .., ..

[4]…295 .., .., .., .., ..

…...296 .., .., .., ..

11-

Ņ298 .., .., .., ..

(1R,4S,6R)-4--7-[4.1.0]-2-300 .., .., .., .., .., .., .., ..

-

ȅ301 .., .., ..

…...303 .., ..

-

̅...304 .., .., ..

305 .., .., .., . ., .., ., .., ..

Ҕ

Ņ..306 .., .., ..

ۅ308 .., .., .., .., .., ..

-

ʅ.309 .., .., .., .., ..

1,2- 1,3- ȅ.310 .., .., .., ., .., ..

[4]

ȅ311 .., .., ..

Յ...312 .., .., ..

…..314 .., .., .., .., .., .., .., ..

-ӻ.315 .., .., .., ., ., .., ..

[2+4]- 1--3-(2--2-)2-..317 .., ..

SCUTELLARIA SCHACHRISTANICA..318 .., .., .., .., ..

…...319 .., .., .., .., ..

2

ȅ320 .., .., .., ..

:

ą...321 ., ..

߅...322 .., .., ..

D-.323 .., .., .., .., ..

(R)-

...324 .., .., .., .., ..

(R,R)- (R,S)--3-

.., .., ..

.326 .., ..

ۅ327 .., .., ..

….328 .., .., .., .., .., ..

һ -

Յ.330 .., .., ..

.332 .., .., .., ..

,

҅...334 .., .., .., .., .., .., ..

҅.335 .., .., .., .., ..

5-ۅ...337 .., .., .., ..

2--N-(-3)-…..339 .., .., ..

-

ȅ...340 .., .., ..

Ʌ...341 .., .., ..

-ܻ343 .., .., .., .., .., .., .., ..

1,3-[5 -2-]-6-

ȅ...344 .., .., ..

7-

1--8--3-…..345 .., .., ..

ARTEMISIA

߅...346 .., .., .., ..

1-[(2E,4E)--2,4]..348 .., .., .., ., .., ..

Ʌ..349 .., ..

Ʌ.351 .., ..

1,3- Յ..353 .., .., ..

̅.355 .., .., .., .., .., .., ..

ޅ..356 ..

HBsAg B. Mori...357 .., .., ..

Ņ358 .., ..

1,3-…...360 .., .., .., .., ..

- ߅...361 .., .., ..

,

Յ362 .., .., .., .., ..

1 13х.363 .., .., .., ..

2,3- ۅ.364

VIII

   

.. 23.03.2010.

60841/8. .

. .

.-.. 45,1. .-.. 44,2.

300 . 18.

450077, . , . , 15 .: (347) 273-05-93, 272-36-82 -mail: gilem@anrb.ru

450077, . , . , 15 .: (347) 273-05-93, 272-36-82

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